UDC 550.47:550.424 + 504 • Issue 7 (35) / 2022 • 38-41 pages
O. Lavrynenko, V. Yatsenko, L. Zaborovskaya, B. Shabalin
Lavrynenko O.M., D. Sc. (Chem.), Leading Researcher, I.M. Frantsevich Institute for Problems of Materials Science of National Academy of Sciences of Ukraine, State Institution “The Institute of Environmental Geochemistry of National Academy of Sciences of Ukraine”, ORCID: 0000-0002-9256-1221, alena.lavrynenko@gmail.com
Yatsenko V.G., PhD (Geol.), Head of Laboratory, State Institution “The Institute of Environmental Geochemistry of National Academy of Sciences of Ukraine”, ORCID: 0000-0003-3498-3466, vgyatsenko@gmail.com
Zaborovskaya L.P., PhD (Geol.), Senior Researcher, State Institution “The Institute of Environmental Geochemistry of National Academy of Sciences of Ukraine”, ORCID: 0000-0001-7848-5528, zaborovskayalp63@gmail.com
Shabalin B.G., D. Sc. (Geol.), Head of Department, State Institution “The Institute of Environmental Geochemistry of National Academy of Sciences of Ukraine”, ORCID: 0000-0002-6425-5999, b_shabalin@ukr.net
Abstract
Using XRF, TG-DTA, and chemical analysis of the products of processing of magnetite quartzites from the N Ore Processing Plant of Krivorozhye, changes in the phase and chemical composition of samples of four stages of magnetic separation and tailings were traced compared to a sample of the raw ore, and the potential impact of the dispersion process on the environment was revealed. Thermogravimetric studies indicate phase transformations of magnetite to maghemite (250–340°C), polymorphic transformations of iron oxides and destruction of rock-forming minerals (430–480°C), conversion of quartz to alpha form (564–568°C), dehydroxylation of iron and magnesium oxyhydroxides (385°C), conversion of alpha quartz to beta – cristobalite (970°C). In the process of enrichment, there is an increase in the loss of mass of the samples, which is 0,06% (I), 1,46% (II), 1,9% (III), and 2,6% (IV). According to X-ray diffraction, the main ore mineral is magnetite, the rock-forming mineral is quartz. Among the secondary minerals are sulfides, cummingtonite, actinolite, and others. It is shown that at the first stage of enrichment all primary and secondary minerals are present in the samples, at the 2nd stage sulfides disappear from the sample, at the 3rd stage secondary minerals disappear, and at the 4th stage quartz remains in the sample and it forms aggregates with magnetite. The parameter of the crystal lattice of magnetite varies between 8,397–8,403 nm,
its coherent scattering region is 31,4–35,6 nm. It is found that in the course of ore grinding the destruction of secondary minerals takes place with the removal of destruction products, as evidenced by the occurrence of disperse quartz in the tailings. Analysis of the chemical composition of the dispersion products indicates that Si, Ca, and Na accumulate in the tailings, whereas Ti is removed, and could potentially enter the environment. It is shown that the tailings and separation products increase the content of Zn, and the tailings accumulate environmentally hazardous As, and Nb. At the same time, the concentrations of other elements remain stable at all stages of processing.
Key words: magnetite quartzites, ore beneficiation, dispergation, wet magnetic separation, mineral degradation, environmental safety.
Article
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