Yu. Fomin, V. Verkhovsev, Yu. Demikhov, Z. Kravchuk, N. Borisova, A. Studzinska
Yu. Fomin Candidate of geological-mineralogical sciences, Senior Research Fellow, Leading Researcher State Institution «Institute of Environmental Geochemistry of the NAS of Ukraine», yaf1941@gmail.com.
V.Verkhovsev Doctor of Geology, Senior Research Fellow, Head of department State Institution «Institute of Environmental Geochemistry of the NAS of Ukraine», Verkhovtsev@ukr.net.
Yu. Demikhov Candidate of geological-mineralogical sciences, Senior Research Fellow, Head of the laboratory State Institution «Institute of Environmental Geochemistry of the NAS of Ukraine», y_demikhov@ukr.net.
Z.Kravchuk Lead Engineer State Institution «Institute of Environmental Geochemistry of the NAS of Ukraine», IGNS_Kravchuk@nas.gov.ua.
N.Borisova Lead Engineer State Institution «Institute of Environmental Geochemistry of the NAS of Ukraine», IGNS_Borysova@nas.gov.ua.
A. Studzinska, Junior Research Fellow, State Institution «Institute of Environmental Geochemistry of NAS of Ukraine», anna.studz88@ukr.net
Abstract
Basing on the many-year personal experience of the isotopic study of the Early Cambrian uranium and gold deposits in the Ukrainian shield, the authors consider a number of methodological issues concerning the theory of ore formation, i.e., selection of objects and methods of their testing, sample processing, and interpretation of the obtained results. The article presents the requirements for the geological material for complex isotope studies in the genetic field, which include the methods developed by the laboratory of State Institution “IEG of National Academy of Sciences of Ukraine” for determination of the isotopic sulfur composition of sulphides and sulphates, gross carbon of rocks along with the analysis, if necessary, of carbonate and organic (+ graphite) components, carbon and oxygen of carbonates, oxygen of oxides without the silicon base, as well as quartz and silicates, hydrogen and oxygen of hydroxyl-containing minerals, hydrogen, oxygen and carbon of fluid inclusions in minerals. The necessity of the preliminary systematic study of the selected objects to develop a reliable geological basis and special concern for the material composition of ores with the separation and systematization of the mineral compounds is emphasized.
Key words: isotopic geochemistry, theory of ore formation, uranium and gold deposits, methods for determining the isotopic composition, material composition of ores.
Article
Reference
- A. Kazhdan, N. Solov’ev. Poiski i razvedka mestorozhdenij redkih i radioaktivnyh metallov. [Search and exploration of deposits of rare and radioactive metals] – Moskva: Nedra, 1982. – 280 s [in Russian].
- J. Hyofs. Geohimiya stabil’nyh izotopov [Geochemistry of stable isotopes] – Moskva: Mir, 1983. – 200 s [in Russian].
- U. Dir, R. Haui, Dzh Zusman. Porodoobrazuyushchie mineraly [Species-forming minerals]. – Moskva: Mir. T.1, 1965. – 371 s. T.2, 1965. – 406 s. T.3, 1966. – 317 s. T.5, 1966. – 406 s [in Russian].
- Yu. Fomin, Yu Demihov. Sul’fidnaya sistema v ranneproterozojskih porodah checheleevskogo litologo-stratigraficheskogo urovnya Kirovogradskogo megabloka (Ukrainskij shchit) [Sulfide system in the Early Proterozoic rocks of the Checheleyev lithologic-stratigraphic level of the Kirovograd megablock (Ukrainian Shield)] // Geohіmіya ta ekologіya. – Kiїv. – 2010. – Vip. 18. – S. 80-90. // Geochemistry and Ecology, Kyiv, 2010, № 18, P. 80-90 [in Russian].
- Metody izucheniya uranovyh mestorozhdenij v osadochnyh i metamorficheskih tolshchah [Methods of studying uranium deposits in sedimentary and metamorphic sequences] / Pod red. Ya. Belevceva i V. Dancheva. – Moskva: Nedra, 1985. – 323 s [in Russian].
- Yu. Fomin.A., E. Lazarenko. Temperatura formirovaniya zolotogo i uranovogo orudeneniya Yur’evskogo mestorozhdeniya (Ukrainskij shchit) [Temperature formation of gold and uranium mineralization of the Yurievske deposit (Ukrainian Shield)] // Dop. NAN Ukraїni. – 2009. – № 7. – S. 114-120 [in Russian].
- V. Kobzar’. Nizhneproterozojskoe osadkonakoplenie i voprosy metallogenii central’noj chasti Ukrainskogo shchita [Proterozoic sedimentation and questions of metallogeny of the central part of the Ukrainian Shield]. – Kiev: Nauk. dumka, 1981. – 104 s. [in Russian].
- Yu. Fomin, Yu. Demihov, E. Lazarenko, S. Tereshchenko. Priroda karbonatov Severinovskogo mestorozhdeniya urana (Ukrainskij shchit) [ The nature of carbonates of the Severinovske uranium deposit (Ukrainian Shield)] // Geohіmіya ta ekologіya. – Kiїv. – 2002. – Vip. 5/6. – S. 124-132 [in Russian].
- Yu. Fomin. Vostochno-Yur’evskoe mestorozhdenie zolota [East-Yuryev gold deposit] // Min. zhurn. – 1999. – 21. – №4. – S. 32-44 [in Russian].
- Yu. Fomin, L. Savchenko, A. Ivanov. Priroda magnetita zolotonosnyh zelenokamennyh struktur Srednego Pridneprov’ya (po izotopnym i geohimicheskim dannym) [The nature of the magnetite of the gold-bearing greenstone structures of the Middle Dnieper (by isotope and geochemical data] // Min. zhurn. – 1995. – 17. – № 3. – S. 67-73.) [in Russian].
- I. Lugovaya, L. Savchenko. Izotopno-geohimicheskie osobennosti formirovaniya vulkanogenno-osadochnyh i terrigenno-hemogenno-osadochnyh zhelezorudnyh mestorozhdenij Ukrainskogo shchita [Isotope-geochemical features of the formation of volcanic-sedimentary and terrigenous-chemogenic-sedimentary iron ore deposits of the Ukrainian Shield] / Izotopnaya geohimiya processa rudoobrazovaniya. – Moskva: Nauka, 1988. – S. 216-233 [in Russian].
- F. Berezovsky, Yu. Demikhov , I. Korostyshevsky, N. Lyuta. Vzaimodejstvie gidro-galogenidov guanidina s kislorodsoderzhashchimi veshchestvami – metod vydeleniya kisloroda dlya izotopnogo analiza [Interaction of hydro-halides of guanidine with oxygen-containing substances – the method of oxygen release for isotopic analysis] // Zhurnal analitich. himii. – T. 40.– № 10, 1985. – S. 1848-1853 [in Russian].
- V. Melnikov. Geneticheskoe znachenie inversionnogo perekhoda sanidin/mikroklin. 1. Flyuidnyj faktor v transformacii dvojnikovoj struktury shchelochnyh polevyh shpatov [The genetic significance of the sanidine/microcline inversion transition. 1. Fluid Factor in the Transformation of the Twin Structure of Alkaline Feldspars ] // Min. zhurn. – 2009. –31. – № 4. – S. 16-29 [in Russian].
- Yu. Fomin, E. Lazarenko. Shchelochnye polevye shpaty uranonosnyh al’bititov Ukrainskogo shchita [Alkaline feldspars of uranium-bearing albitites of the Ukrainian shield] // Geohіmіya ta ekologіya. – Kiїv. – 2010. – Vip. 18. – S. 57-72 [in Russian].
- S. Solovyov. Himizm magmaticheskih gornyh porod i nekotorye voprosy petrohimii [Chemistry of igneous rocks and some questions of petrochemistry]. – Leningrad: Nauka, 1970. – 312 s [in Russian].